4.6 Article

Facile synthesis of 3D networks of C/SnOx/C hybrid nanofibers with enhanced lithium storage

Journal

MATERIALS LETTERS
Volume 116, Issue -, Pages 271-274

Publisher

ELSEVIER SCIENCE BV
DOI: 10.1016/j.matlet.2013.11.015

Keywords

Composite materials; Deposition; Semiconductors; Energy storage and conversion; Networks

Funding

  1. National Natural Science Foundation of China [11179038, 10974073]
  2. Specialized Research Fund for the Doctoral Program of Higher Education [20120211130005]

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3D networks consisted of C/SnOx/C hybrid nanofibers were prepared by a simple dip-coating process and subsequent CVD growth. The as-prepared material, worked as a binder-free anode electrode, delivered a reversible capacity of 512 mA h g(-1) after 200 cycles at a current density of 200 mA g(-1). The improved electrochemical performance can be ascribed to the morphological stability and the low resistance of the nanofibers with the CVD carbon skin. Furthermore, the embedded and de-aggregated SnOx nanoparticles in the carbon matrix provide large numbers of reaction sites for lithium ions. The results imply that 3D C/SnOx/C network nanocomposites have potential application in high-performance lithium ion batteries. (C) 2013 Elsevier B.V. All rights reserved.

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