4.6 Article

Hierarchically structured functionalizable mesoporous PEDOT-derived conducting polymers

Journal

MATERIALS LETTERS
Volume 96, Issue -, Pages 181-184

Publisher

ELSEVIER SCIENCE BV
DOI: 10.1016/j.matlet.2013.01.048

Keywords

Porous materials; Polymeric composites; Polymers

Funding

  1. Gyeonggi Technology Development Program [A08091210]
  2. National Research Foundation of Korea (NRF)
  3. Ministry of Education, Science and Technology [2010-0010096]
  4. Gyeonggi Province
  5. National Research Foundation of Korea [2010-0010096] Funding Source: Korea Institute of Science & Technology Information (KISTI), National Science & Technology Information Service (NTIS)

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Chemically functionalizable carboxy group-containing mesoporous poly(3,4-ethylenedioxythiophene) (PEDOT) derivatives, C1-CT/PEDOT/PSS and C4-CT/PEDOT/PSS, with hierarchical particle morphology were prepared in the presence of sacrificial acid-labile ZnO/Zn(OH)(2) hard template. The hard template could be effectively removed by acid etching. The electrical properties and surface texture of the mesoporous PEDOT derivatives were investigated. The chemical accessibility of the carboxy groups in the PEDOT materials was successfully demonstrated by conjugation with green fluorescent 5-aminofluorescein (AFL). AFL-conjugated AFL-C4-CT/PEDOT/PSS particles exhibited uniform green fluorescence under a fluorescence microscope. (C) 2013 Elsevier B.V. All rights reserved.

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