Journal
MATERIALS LETTERS
Volume 79, Issue -, Pages 75-77Publisher
ELSEVIER SCIENCE BV
DOI: 10.1016/j.matlet.2012.03.112
Keywords
Nanoparticles; Crystal structure; Phase transformation; ZrO2; Li+
Funding
- Fundamental Research Funds for the Central Universities
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It is well known that monoclinic ZrO2 nanocrystals can be synthesized at similar to 1000 degrees C by sol-gel method. In this letter, we demonstrate a novel method to synthesize monoclinic ZrO2 nanocrystal through sol-gel technique under relatively lower calcined temperature. It is found that composition of monoclinic ZrO2 can be significantly enhanced by doping Li+, and pure monoclinic phase ZrO2 nanocrystals appear at 900 degrees C. 800 degrees C and 700 degrees C for samples doped with 0.5, 2, and 5 mol% Li+, respectively. This phase transformation of ZrO2 is dependent on the crystallite size and there is a range of around 11-35 nm of crystallite size in which tetragonal and monoclinic ZrO2 coexist. Crown Copyright (C) 2012 Published by Elsevier B.V. All rights reserved.
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