Journal
MATERIALS LETTERS
Volume 66, Issue 1, Pages 374-376Publisher
ELSEVIER SCIENCE BV
DOI: 10.1016/j.matlet.2011.08.093
Keywords
LiFePO4; Nanopolyhedrons; Microellipsoids; Composite materials; Electrical properties
Funding
- National Nature Science Fund of China [91022033]
- 973 Project of China [2011CB935900]
- Fundamental Research Funds for the Central Universities [WK 2340000027]
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LiFePO4 nanopolyhedrons with the size of -200 nm have been solvothermally synthesized in the binary solvent of benzyl alcohol and ethylene glycol. As citric acid added, microellipsoids with an average size of 1 mu m were formed. LiFePO4 nanopolyhedrons and microellipsoids were coated by carbon layers using cellulose acetate as carbon source. Electrochemical measurements showed that the LiFePO4/C nanopolyhedrons could deliver a discharge capacity of 145 mAh g(-1) under 1 C and had a capacity decay rate of <11% after 200 cycles, while the LiFePO4/C microellipsoids had a discharge capacity of 123 mAh g(-1) under 1 C and the capacity decay rate was less than 8% after 200 cycles. (C) 2011 Elsevier B.V. All rights reserved.
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