4.6 Article

Mechanochromic luminescence of 4-[bis(4-methylphenyl)amino]benzaldehyde

Journal

MATERIALS LETTERS
Volume 65, Issue 17-18, Pages 2658-2661

Publisher

ELSEVIER SCIENCE BV
DOI: 10.1016/j.matlet.2011.05.068

Keywords

Fluorescent material; Mechanochromic luminescence; Solvatofluorochromism; Morphology; Twisted intramolecular charge transfer

Funding

  1. Grants-in-Aid for Scientific Research [23550209, 20246058, 21550171] Funding Source: KAKEN

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The title compound was found to exhibit mechanochromic luminescence: the fluorescent color of the crystalline powder was changed from light blue to greenish yellow by grinding and then returned to the original by keeping at room temperature. The phenomenon was suggested to be due to formation of the supercooled liquid state of the material by grinding and following recrystallization. (C) 2011 Elsevier BM. All rights reserved.

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