4.6 Article

α-Fe-incorporated nanoporous carbon with magnetic properties

Journal

MATERIALS LETTERS
Volume 63, Issue 13-14, Pages 1177-1179

Publisher

ELSEVIER SCIENCE BV
DOI: 10.1016/j.matlet.2009.02.023

Keywords

Casting; Composite materials; Magnetic materials; Porosity

Funding

  1. Shandong Province [Y2007B29, Y2008F36, 2008BS09007]
  2. Shandong University of Technology [2006KJM17]

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A kind of magnetic nanoporous carbon (MNC) has been synthesized through nanocasting strategy by using ordered mesoporous silica as a hard template and sugar as a carbon source. Small angle X-ray diffraction measurements show that MNC basically resembles the pore symmetry of the template, namely, two-dimensional (21)) hexagonal mesostructure with P6mm space group. Results also indicate that, the introduced iron precursor, Fe(NO3)(3)center dot 9H(2)O, was decomposed and in-situ confined within the carbon framework, being present in a form of alpha-Fe nanoparticles, which results in superparamagnetic property and good separability of MNC. As evidenced by desorption kinetic studies, MNC is a very promising carrier for drug delivery applications. (C) 2009 Elsevier B.V. All rights reserved.

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