4.6 Article

Synthesis of mesoporous Co-B alloy in room-temperature ionic liquids and its electrochemical properties

Journal

MATERIALS LETTERS
Volume 63, Issue 17, Pages 1555-1557

Publisher

ELSEVIER
DOI: 10.1016/j.matlet.2009.04.016

Keywords

Amorphous Co-B; Nanocomposites; Nanomaterials; Room-temperature ionic liquids; Electrochemical property; Mesoporous structure

Funding

  1. CIDUT [2007-YG2, HZ0033]
  2. Natural Science Foundation of Sichuan Province [07ZA004]

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Co-B alloy with mesoporous structure was firstly synthesized using room-temperature ionic liquids as templates and investigated as an anode for secondary alkaline batteries. Investigations indicate that such mesoporous structure facilitated the electrochemical hydrogen storage. It maintained 94% of the initial capacity (336 mA h/g) after 50 cycles. The excellent cycling performance is most likely due to the stable structure during cycling. Meanwhile, it exhibited an excellent rate capability. The results demonstrated that the prepared Co-B-mesoporous is capable of serving as a high power capability anode for the rechargeable alkaline batteries. (C) 2009 Elsevier B.V. All rights reserved.

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