Journal
MATERIALS CHEMISTRY AND PHYSICS
Volume 147, Issue 3, Pages 744-750Publisher
ELSEVIER SCIENCE SA
DOI: 10.1016/j.matchemphys.2014.06.015
Keywords
Composite materials; Organometallic compounds; Microporous materials; Nanostructures; Electrical characterisation
Categories
Funding
- Accordo CNR-MSE Utilizzo pulito dei combustibili fossili ai fini del risparmio energetico
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Metal-organic framework (MOP) incorporating conductive graphene-like layers were synthesized and characterized. The selected MOF, HKUST-1, combines high surface area, water stability, simple preparation and low costs. Graphene-like layers incorporated into the MOF structure were obtained by a two-step oxidation/reduction wet treatment of a high surface carbon black. MOF composites were produced at different carbonaceous layers content. It was shown, through a wide characterization of the samples, that the composites preserve the main features of the parent MOF, additional exhibiting a tunable electrical conductivity. (C) 2014 Elsevier B.V. All rights reserved.
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