4.6 Article

The effect of inserted gold nanosphere on the local field enhancement of gold nanoshell

Journal

MATERIALS CHEMISTRY AND PHYSICS
Volume 133, Issue 2-3, Pages 1060-1065

Publisher

ELSEVIER SCIENCE SA
DOI: 10.1016/j.matchemphys.2012.02.016

Keywords

gold-dielectric-gold nanoshells; Multilayer nanoshells; Local field enhancement; Localized surface plasmon resonance

Funding

  1. National Natural Science Foundation of China [11174232, 61178075, 81101122]
  2. Fundamental Research Funds for the Central Universities

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Because of the hybridized coupling between the bonding shell plasmon and the inserted sphere plasmon, there are two major peaks in the local field enhancement spectra of gold-dielectric-gold multi-nanoshells. The inserted gold nanosphere takes great effect on the local electric field enhancement at different interfaces and locations of this multilayer core-shell nanostructure. In the case with small thickness of the outer gold shell, the interaction between the inner and outer surface of the gold shell is intense. Increasing radius of the inserted gold sphere always leads to the longer wavelength peak red shift and the shorter wavelength peak blue shift. However, the way the local field intensity changes as a function of inserted gold sphere size is different at different location. In the case with large thickness of the outer gold shell, the interaction between inserted gold sphere and inner surface of the gold shell takes major effect and greatly depends on the radius of the inserted gold sphere. Thus the effects of inserted gold sphere on the local field enhancement are different from the case with thin gold shell. Blend and split of local field enhancement peaks take place in this case when the size of inserted gold sphere is changed. (C) 2012 Elsevier B.V. All rights reserved.

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