Journal
MATERIALS CHEMISTRY AND PHYSICS
Volume 130, Issue 1-2, Pages 367-372Publisher
ELSEVIER SCIENCE SA
DOI: 10.1016/j.matchemphys.2011.06.050
Keywords
Composite materials; Nanostructures; Chemical synthesis; Supercapacitor
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Funding
- Taiwan Textile Research Institute
- National Science Council, Taiwan, ROC [NSC 98-2221-E-002-084-MY3, 98-3114-E-007-011]
- King Abdullah University of Science and Technology (KAUST) [KUK-C1-014-12]
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MnO2 has been deposited onto two types of carbon (C) substrates, including a non-porous multi-wall carbon nano-tube (CNT) and a porous carbon black (CB) powder, by a solution reduction process where MnO4- was reduced at 80 degrees C by the C substrate so as to give nano-crystalline MnO2 directly at the C surface. The nature of the C substrate has profound effects on polymorphicity, microstructure and electrochemical properties, in terms of supercapacitor application, of the resulting oxide. Deposition on CNT produces meso/macro-porous layer containing predominantly spinel MnO2 strongly bonded to the CNTs and having a larger surface area, while that on CB results in birnessite granules with a lower surface area. In addition to having a higher specific capacitance (309 Fg(-1)), the MnO2/CNT electrode exhibits superior power performance (221 Fg(-1) at 500 mV s(-1) or ca. 20 Wh kg at 88 kW kg(-1)) to MnO2/CB due to reduced electronic and ion-diffusion resistances. Furthermore, the MnO2/CNT electrode also exhibits slower self-discharging rate and greater cycling stability. The results indicate that the MnO2 spinel/CNT holds promise for supercapacitor applications. (C) 2011 Elsevier B.V. All rights reserved.
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