Journal
MATERIALS CHEMISTRY AND PHYSICS
Volume 120, Issue 1, Pages 181-186Publisher
ELSEVIER SCIENCE SA
DOI: 10.1016/j.matchemphys.2009.10.043
Keywords
Nanostructures; Flame; Chemical vapor deposition (CVD); Electrochemical properties; DSSC; TiO2
Categories
Funding
- National Science Council of Taiwan [NSC-93-2216-E-259-003, NSC-94-2623-7-259-001-ET]
- FE-SEM [NSC-96-2120-M-259-001]
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A unique method of flat-flame chemical vapor deposition, to synthesize nanostructured TiO2 film used for dye-sensitized solar cells (DSSCs) is reported for the first time. This method produces nanostructures of TiO2 exactly ideal for the anode of the DSSCs. Results show that cells have characteristic I-V curves with fill factor typically around 70% and efficiency higher than 4%. A dendrite-like microstructure of anodes accounts for the high efficiency of the cell. The successful formation of dendrite-like microstructure provides a chance for sintering of TiO2 nanoparticles smaller than 20 nm, a possible cell efficiency enhancement by increased dye absorption due to the increased specific surface area of small particles. (C) 2009 Elsevier B.V. All rights reserved.
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