4.6 Article

Fabrication of polystyrene hollow spheres in W/O/W multiple emulsions

Journal

MATERIALS CHEMISTRY AND PHYSICS
Volume 124, Issue 1, Pages 10-12

Publisher

ELSEVIER SCIENCE SA
DOI: 10.1016/j.matchemphys.2010.06.010

Keywords

Multilayers; Polymers; Coatings; Electron microscopy

Funding

  1. National Science Foundation for Post-doctoral Scientists of China [20090451256]
  2. Ph.D. Programs Foundation of Ministry of Education of China [20090095120011]
  3. Fundamental Research Funds for the Central Universities
  4. Scientific Research Foundation for the Returned Overseas Chinese Scholars, State Education Ministry

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One mild multiple emulsions was used for the fabrication of hollow polystyrene (PS) spheres. Polystyrene was dissolved in a volatile organic solvent to form the O phase, then an aqueous phase containing a surfactant was transferred into above phase to form an oil-in-water (W-in/O) emulsion, followed by addition of W-in/O emulsion in the external W-out phase, and solvent evaporation. Final product with diameter of 150 mu m, surface roughness of 30 nm, and sphericity of 98.0% was obtained. The possible influences on the formation of PS hollow sphere were also discussed. Crown Copyright (C) 2010 Published by Elsevier B.V. All rights reserved.

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