Journal
MATERIALS CHEMISTRY AND PHYSICS
Volume 110, Issue 2-3, Pages 299-302Publisher
ELSEVIER SCIENCE SA
DOI: 10.1016/j.matchemphys.2008.02.023
Keywords
thin films; chemical vapor deposition (CVD); Fourier transform infrared spectroscopy (FTIR); X-ray photoelectron spectroscopy (XPS)
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The characterizations of SiOCH films using oxygen plasma treatment depends linearly on the O-2/CO flow rate ratio. According to the results of Fourier transform infrared spectroscopy (FTIR) and X-ray photoelectron spectroscopy (XPS) analyses, it was found that the carbon composition decreases with increasing O-2/CO flow rate ratio, because more carbon in the Si-O-C and Si-CH3 bonds on the film surface would be converted by oxygen radicals. It was believed that the oxygen plasma could oxidize the SiOCH films and form a SiOx interfacial capping layer without much porosity. Moreover, the result of FTIR analysis revealed that there was no water absorbed on the film. A SiO2-like capping layer formed at the SiOCH film by the O-2/CO flow rate ratio of 0.75 had nearly the same dielectric properties from the result of capacitance-voltage (C-V) measurement in our research. (C) 2008 Elsevier B.V. All rights reserved.
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