Journal
MATERIALS AND STRUCTURES
Volume 47, Issue 3, Pages 533-539Publisher
SPRINGER
DOI: 10.1617/s11527-013-0077-6
Keywords
Phase-change materials; Latent heat storage; Expanded graphite; Butyl stearate; Gypsum; Building energy conservation
Categories
Funding
- Zhejiang Provincial Natural Science Foundation [LY12E08019]
- National Basic Research Program of China [2009CB623203]
- Key Science and Technology Innovation Team of Zhejiang Province [2010R50034]
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A new method to manufacture gypsum-based building materials with high latent heat storage capability is described. When expanded graphite is used as the adsorption medium for butyl stearate, an organic/inorganic phase-change composite is formed. This composite can be mixed with gypsum to manufacture a latent heat storage gypsum-based building material. Differential scanning calorimetry (DSC) test results indicate that the phase-change enthalpy value of this composite is similar to that of pure butyl stearate and that it therefore displays good thermophysical properties. We found that a mixture of gypsum with this composite should contain no more than 5 % of the latter to maintain the workability of the paste. The hardened gypsum-composite material exhibits some defects in the interface between the phase-change composite and the gypsum, but these do not seriously affect the strength of the gypsum product. The results of a temperature cycle test illustrate that gypsum containing 5 % phase-change composite can deliver high-performance heat storage/release. This characteristic of the composite will improve the inertia of ambient temperature fluctuations, making it applicable as a new building product that will conserve energy.
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