Journal
APPLIED SURFACE SCIENCE
Volume 326, Issue -, Pages 236-242Publisher
ELSEVIER
DOI: 10.1016/j.apsusc.2014.11.121
Keywords
Thermally reduced GO; Temperature dependent electrical; conductivity; Activation energy; sp(2)/sp(3) fraction; Band gap
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Temperature dependent electrical conductivity of as prepared and thermally reduced graphene oxide (GO) thin films was measured in the range 300-520 K. As prepared GO films show very low conductivity similar to 6.8 x 10(-6) S/cm at 300 K, which increases slowly till 370K. A sharp increase in conductivity is observed in the temperature range 370-440 K, beyond which conductivity is thermally activated with activation energy 0.26 eV. Reduced GO films show an increase in conductivity at 300 K with increase in reduction temperature. GO films reduced at 400 C exhibit high conductivity similar to 40 S/cm at 300 K, with very low activation energy 0.05 eV in the measured temperature range 300-520 K. The increase in conductivity after thermal reduction is due to an increase in the ratio sp(2)/sp(3) bonded carbon atoms. The band gap of as prepared GO is 3.20 eV and it is decreased by approximately 0.4 eV in the case of thermally reduced GO at 400 degrees C in comparison to as prepared GO. (C) 2014 Elsevier B.V. All rights reserved.
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