Growth kinetics and microstructure of MOCVD iridium coating from iridium(III) acetylacetonate with hydrogen

Iridium coatings were produced by metallo-organic chemical vapor deposition (MOCVD) using iridium(III) acetylacetonate (Ir(acac)(3)) as precursor at 400-520 degrees C under atmospheric pressure in the presence of hydrogen. Three different deposition regions were obtained in the study: reaction-rate-limited regions at intermediate (460-500 degrees C), low (<460 degrees C), and high (520, and 540 degrees C) temperatures. The steady-state kinetics of iridium deposition was studied as functions of temperature and hydrogen pressure at intermediate temperatures, which could be described with the Rideal-Elay kinetic model. This model indicates that the hydrogen in the air is activated and reacts with the Ir(acac)3 molecules adsorbed on the surface. At high temperatures, growth velocity was changed into the relation dependent more on deposition temperature and hydrogen partial pressure, while at low temperatures stable deposition results could not be obtained in the system. The coating microstructure strongly depended on deposition temperature and hydrogen pressure. The coatings surfaces show an even topography in the reaction-limited regions and uneven ones at low or high deposition temperatures. The grain size increased with decreased temperature or decreased hydrogen pressure at 400-500 degrees C. (C) 2014 Elsevier B.V. All rights reserved.