Journal
MACROMOLECULES
Volume 47, Issue 11, Pages 3625-3634Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ma500072j
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Funding
- National Science Foundation, Polymers Program [DMR-0907128, DMR-1310196]
- Division Of Materials Research
- Direct For Mathematical & Physical Scien [1310196] Funding Source: National Science Foundation
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We investigate the influence of nanofiller surface chemistry and ion content on the conductivity of nanofilled PEO + LiClO4 solid polymer electrolytes (SPEs) using dielectric spectroscopy, differential scanning calorimetry (DSC), FESEM, and quasi-elastic neutron scattering (QENS). We consider the concentration series EO/Li = 8:1, 10:1 (eutectic composition), 14:1, with both acidic alpha-Al2O3 and neutral gamma-Al2O3 nanoparticles. The acidic filler is more effective at increasing conductivity at the non-eutectic compositions. In contrast, the two surface chemistries provide comparable increases at the eutectic composition. This composition maximizes the influence of nanofillers, regardless of surface chemistry. We find no significant changes in crystallinity, glass transition temperature, nanoparticle dispersion, or PEO segmental dynamics as a function of surface chemistry. In the absence of salt, acidic particles slow PEO dynamics more than neutral particles, suggesting that the PEO chains and the acidic surface sites share a favorable interaction. A rotation consistent with the crystal structure PEO6:LiClO4 is observed up to 50 degrees C (8:1) and up to 75 degrees C (eutectic composition). PEO6 rotation is hindered by nanoparticles, with the degree of restriction as a function of surface chemistry. We propose a mechanism where nanofillers stabilize the PEO6 structure at their surface, and differences in surface chemistry and composition dictate the extent of stabilized PEO6 and whether Li movement in this structure is facile or restricted.
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