Spiral and Mesoporous Block Polymer Nanofibers Generated in Confined Nanochannels

Spiral-like or various porous polymer nanofibers have great applications in biosensor, bioengineering, and template-fabrication of functional inorganic materials. However, the fabrication of polymer nanostructures with controllable porous or spiral morphology in one process is a big challenge. Here we first demonstrated a general and easy method to generate spiral or porous block copolymer (BCP) nanofibers by using geometric confinement of nanochannels to disturb the self-assembly of BCP while nonsolvent is induced into BCP solution. Continuous spiral polymer nanofibers and polymer nanofibers with hierarchical porous nanostructures can be easily generated within channels of anodic aluminum oxide (AAO) membranes by tuning the composition and concentration of BCP. This study first reports the influence of cylinder confinement to the arrangement of BCP micelles. These spiral and porous BCP nanostructures are not only good templates to generate functional inorganic nanostructures, but also promising candidates to create biosensors or to load catalyst because their enlarged surface area enables high guest concentrations.