Journal
MACROMOLECULES
Volume 46, Issue 16, Pages 6408-6418Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ma401030m
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Funding
- Fonds de recherche quebecois sur la nature et les technologies (FRQNT)
- Natural Sciences and Engineering Research Council of Canada (NSERC)
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The synthesis of four amphiphilic thieno[3,4-c]pyrrole-4,6-dione (TPD)-based alternating copolymers and their behavior at the air-water interface are reported. Homogeneous and stable monolayers of TPD-based copolymers were prepared. Brewster angle microscopy (BAM) was utilized to characterize the morphology and topography of these Langmuir films, UV-vis absorption spectroscopy as well as atomic force microscopy has revealed a regular transfer of some copolymers on glass substrates. It was possible to obtain homogeneous Langmuir-Blodgett films of up to 30 layers. Infrared dichroic measurements revealed an edge-on orientation. These Langmuir-Blodgett films made of conjugated polymers are therefore good candidates for organic field-effect transistors (OFETs).
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