4.7 Article

Reorientation of Microphase-Separated Structures in Water-Suspended Block Copolymer Nanoparticles through Microwave Annealing

Journal

MACROMOLECULES
Volume 46, Issue 10, Pages 4064-4068

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/ma400620v

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Funding

  1. MEXT, Japan [23109502]

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We describe here the first report for developing microphase-separated structures in poly(styrene-block-isoprene) (PS-b-PI) block copolymer nanoparticles by microwave annealing in a nonsolvent, water. A random structure in the nanoparticles successfully transformed to thermodynamically stable structures within several minutes though it takes several days by using the conventional thermal annealing process.

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