Journal
MACROMOLECULES
Volume 46, Issue 18, Pages 7173-7179Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ma401007b
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- National Science Council
- National Taiwan University
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Ring-opening metathesis polymerization (ROMP) of cyclobutenes fused with N-arylpyrrolidene with Schrock-Hoveyda catalyst containing a racemic biphenolate ligand [Mo(N-2,6-i-Pr2C6H3)(CHCMe2Ph)(biphenolate)] gives polycyclobutenes with homogeneous tacticity and predominantly double bonds in Z-configuration. Reactions of the same substrates with the first-generation Grubbs catalyst [(Cy3P)(2)Cl2Ru=CHPh] or Schrock molybdenum carbene with monodendate alkoxy ligandS [Mo(N-2,6-i-Pr2C6H3)(CHCMe2Ph)(OCMe(CF3)(2)] yield the corresponding polycyclobutene containing a mixture of Z- and E-double bonds. Upon diimide reduction, all these polycyclobutenes give the same tactic hydrogenated polymers, indicating that the stereochemistry at the asymmetric carbons remains the same in all these reactions. The stereoselectivities of ROMP with cyclobutenes and with norbornenes are compared, and the plausible mechanisms are proposed.
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