Journal
MACROMOLECULES
Volume 46, Issue 13, Pages 5195-5201Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ma400659h
Keywords
-
Categories
Funding
- German Science Foundation (DFG) [TH 1104/4-1]
- International Collaboration in Chemistry award from the National Science Foundation [CHE 0924435]
- WCU (World Class University) program through the National Research Foundation of Korea
- Ministry of Education, Science and Technology [R31-10013]
- US department of Energy (DOE) [DOE DE-FG02-96ER45612]
- Division Of Chemistry
- Direct For Mathematical & Physical Scien [0924435] Funding Source: National Science Foundation
Ask authors/readers for more resources
A series of poly(pentafluorophenyl (methyl)acrylates)-block-poly-(ethylene oxide) with o-nitrobenzyl ester photocleavable junctions (PPFP(M)A-hv-PEO) were synthesized by RAFT polymerization. The block copolymers were used to fabricate thin films and fibers by spin-coating and electrospinning, respectively. After solvent annealing, UV exposure, and washing with methanol/water to remove the minor PEO block, nanoporous structures were obtained. Both the porous thin films and fibers remained reactive to amine substitution of the pentafluorophenyl esters under mild conditions, which was confirmed by XPS, fluorescence confocal microscopy, FT-IR, and contact angle measurements.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available