Journal
MACROMOLECULES
Volume 45, Issue 19, Pages 7770-7777Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ma301797w
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Funding
- DFG [SPP 1355, KI-1094/4]
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Ni-catalyzed polymerization of anion-radical complexes formed upon mixing of 2,6-bis(2-bromothien-5-yl)-naphthalene-1,4,5,8-tetracarboxylic-N,N'-bis(2-octyldodecyl) dii-mide and activated Zn powder was investigated. We provide experimental evidence that the polymerization involves the chain-growth mechanism and proceeds via Ni(0) complexes which were previously proposed to be key intermediates in other chain-growth catalyst-transfer polycondensations (CTPs), such as Kumada CTP of thiophenic monomers. DFT calculations predict a remarkable stability of the naphthalene diimide-based Ni(0) complexes. A plausible polymerization mechanism is proposed.
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