Journal
MACROMOLECULES
Volume 44, Issue 15, Pages 6017-6025Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ma200846v
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Funding
- Katholieke Universiteit Leuven (GOA)
- Fund for Scientific Research (FWO-Vlaanderen)
- FRS-FNRS
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Polythiophenes with alcohol, tosylate, azide, ethynylene, carboxylic acid, and amine end groups were prepared by a combination of functionalized nickel initiators and postpolymerization reactions. The azide and ethynylene polymers were subsequently used in a click reaction to produce a conjugated block copolymer. Finally, a conjugated triblock-copolymer was synthesized by means of a chain growth polymerization initiated by a binuclear nickel initiator.
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