Journal
MACROMOLECULES
Volume 44, Issue 16, Pages 6433-6440Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ma201416b
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Funding
- German Science Foundation (DFG) [TH 1104/4-1]
- National Science Foundation [CHE 0924435]
- Ministry of Education, Science and Technology [R31-10013]
- Division Of Chemistry
- Direct For Mathematical & Physical Scien [0924435] Funding Source: National Science Foundation
- Division Of Materials Research
- Direct For Mathematical & Physical Scien [820506] Funding Source: National Science Foundation
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Poly(styrene-block-ethylene oxide) with an o-nitrobenzyl ester photocleavable junction (PS-hv-PEO) was synthesized by a combined RAFT polymerization and click chemistry approach and represents the first report utilizing this method for the synthesis of photocleavable block copolymers. After solvent annealing, highly ordered thin films were prepared from PS-hv-PEO. Following a very mild UV exposure and successive washing with water, PS-hv-PEO thin films were transformed into highly ordered nanoporous thin PS films with pore diameters of 15-20 nm and long range ordering (over 2 mu m x 2 mu m). Afterwards the pores were filled with PDMS by spin-coating in combination with capillary forces. After treatment with oxygen plasma to remove the PS templates, highly ordered arrays of silica nanodots were obtained. This represents the first template application example from highly ordered nanoporous thin films derived from block copolymers featuring a photocleavable junction.
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