Journal
MACROMOLECULES
Volume 44, Issue 17, Pages 6915-6918Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ma2012046
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Funding
- NSF [MRI 0619770, NSF-DMR 0844662, 0955975]
- Petroleum Research Fund [47108-G7]
- Louisiana Board of Regents
- Wayne State University
- ASMS Research Award
- DuPont Young Investigator Award
- Direct For Mathematical & Physical Scien
- Division Of Materials Research [0844662] Funding Source: National Science Foundation
- Division Of Chemistry
- Direct For Mathematical & Physical Scien [0955975] Funding Source: National Science Foundation
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An extra dimension of polymer analysis: ion mobility spectrometry-mass spectrometry (IMS-MS) separates ions according to their size in the gas phase, allowing differentiation of linear and cyclic polymeric isomers. This analytical technique is a rapid and sensitive method for assessing cyclic polymer purity in one step. As highly pure cyclic polymers are crucial for adequately assessing architecture dependent properties, IMS-MS offers great promise in the characterization of this unique class of polymers.
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