Journal
MACROMOLECULES
Volume 43, Issue 15, Pages 6348-6352Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ma100997g
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Funding
- NSF [DMR 0747489]
- Teijin Ltd.
- Division Of Materials Research
- Direct For Mathematical & Physical Scien [0747489] Funding Source: National Science Foundation
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Naphthalene diimide (NDI) copolymers are attractive n-type materials for use in organic electronic devices. Four highly soluble NDI polymers are presented-each differing only in the thiophene content comprising the material. Electron mobilities as high as 0.076 cm(2) V-1 s(-1) for the novel material PNDI-3Th are reported. Polymer crystallinity and general macromolecular order are shown to effectively improve by increasing the number of thiophene units within the polymer backbone. The structure-property relationship of NDI-thiophene copolymers is presented and discussed as it pertains to organic field effect transistor (OFET) performance.
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