Journal
MACROMOLECULES
Volume 43, Issue 18, Pages 7577-7582Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ma101468r
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Funding
- EPSRC [EP/12057865/1, EP/C511794/1]
- NWDA
- University of Liverpool
- Royal Society Wolfson Merit Award Holder
- EPSRC [EP/F057865/1] Funding Source: UKRI
- Engineering and Physical Sciences Research Council [EP/C511794/1, EP/F057865/1] Funding Source: researchfish
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Conjugated polymers derived from thiophene or 3,4-ethylenedioxythiophene derivatives have been widely investigated for use in organic thin-film transistors and organic photovoltaic devices. We describe here the synthesis of a series of conjugated microporous polymers formed by reaction of spiro-bis(2,5-dibromopropylenedioxythiophene) with one of three di- or triethynyl monomers. These polymers have surface areas up to 1631 m(2)/g and exhibit significant microporosity, suggesting possible applications in the fields of organic electronics or optoelectronics.
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