Journal
MACROMOLECULES
Volume 42, Issue 8, Pages 3014-3018Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ma802846g
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Funding
- Department of Science and Technology and National Research Foundation
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A new RAFF agent leaving group based on a triazole moiety is introduced. The triazole moiety plays an active role in the stabilization If the intermediate radical, comparable to the phenyl group in a benzyl leaving group. The newly developed leaving group allows easy conjugation to a large variety of substrates where the triazole linking group is hydrolytically stable. Good control is reported in the polymerizations of vinyl acetate, N-vinylpyrrolidone, n-butyl acrylate, and styrene. The versatility of the method is exemplified by linking the triazole to a phenyl and to an oligosaccharide substrate. Overall, this new RAFT agent leaving group is a useful addition to the limited set of leaving groups reported in literature.
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