Journal
MACROMOLECULES
Volume 41, Issue 20, Pages 7505-7512Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ma800994g
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Funding
- MEXT Japan
- Creation of Nonequilibrium Soft Matter Physics
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The mechanism of instability-driven branching of lamellar crystallites in the formation of polymer spherulites has been examined experimentally for polyethylend-banded spherulites in terms of the molecular weight dependence by optical and atomic force microscopies associated with quenching and chemical etching. The possibility of instability-driven branching has been suggested by the experimental results of our previous work in terms of the temperature dependences of the band spacing, the lamellar width at the growth front, and the growth rate. The examination of the dependences on the average and distribution of molecular weights enables us to differentiate possible origins of the instability, e.g., compositional gradient with the diffusion of uncrystallized fractions and pressure gradient caused by the density difference between the crystal and the melt. The experimental results suggest the instability driven by the pressure gradient in the melt ahead of the growth front.
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