4.3 Article

Enhanced thermal and mechanical properties of lignin/polypropylene wood-plastic composite by using flexible segment-containing reactive compatibilizer

Journal

MACROMOLECULAR RESEARCH
Volume 22, Issue 10, Pages 1084-1089

Publisher

POLYMER SOC KOREA
DOI: 10.1007/s13233-014-2161-3

Keywords

lignin; polypropylene; flexible segment; compatibilizer; wood-plastic composites

Funding

  1. National Natural Science Foundation of China [51163004, 51303034]
  2. Guangxi Universities Scientific Research Project [YB2014165]
  3. Guangxi Natural Science Foundation of China [2013GXNSFAA019308]
  4. Guangxi Small Highland Innovation Team of Talents in Colleges and Universities
  5. Guangxi Funds for Specially-appointed Expert

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A reactive compatibilizer containing flexible segment (RCFS) was synthesized and characterized by Fourier transform infrared spectroscopy (FTIR) and gel permeation chromatography (GPC). The RCFS was used as a compatibilizer for the preparation of lignin/polypropylene (PP) wood plastic composites, and the effect of the RCFS on the properties of composites (e.g., mechanical properties, thermal properties, crystal structure, and morphology) were investigated in detail. Experimental results indicated that the lignin/PP composite displayed the best performance with the addition of 2 wt% RCFS. Its impact strength, flexural strength, and modulus were 56.8%, 37.3%, and 20.6%, respectively, which are higher than those of the untreated composites. Moreover, RCFS treatment could also increase the thermal stability, crystallization rate, and degree of crystallinity of lignin/PP composites.

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