Journal
MACROMOLECULAR REACTION ENGINEERING
Volume 2, Issue 1, Pages 90-98Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/mren.200700042
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Polymerization strategies aiming at further reducing the environmental impact of the already green emulsion polymerization process were investigated. Life cycle assessment showed that non-isothermal strategies starting at low temperature resulted in an environmental impact lower than the isothermal ones. Nevertheless, the major part of the environmental impact was due to raw materials. The effect of the polymerization strategy on polymer microstructure was investigated.
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