Journal
MACROMOLECULAR RAPID COMMUNICATIONS
Volume 35, Issue 10, Pages 987-991Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/marc.201400048
Keywords
host-guest system; pillararene; self-assembly; supramolecular chemistry
Categories
Funding
- National Natural Science Foundation of China [21202145]
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A linear supramolecular polymer based on the self-assembly of an easily available copillar[5]arene monomer is efficiently prepared, which is evidenced by the NMR spectroscopy, viscosity measurement, and DOSY experiment. The single-crystal X-ray analysis reveals that the polymerization of the AB-type monomer is driven by the quadruple CH center dot center dot center dot interactions and one CH center dot center dot center dot O interaction.
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