4.7 Article

Polydiacetylene-Peptide 1D Nanomaterials

Journal

MACROMOLECULAR RAPID COMMUNICATIONS
Volume 34, Issue 17, Pages 1343-1350

Publisher

WILEY-V C H VERLAG GMBH
DOI: 10.1002/marc.201300423

Keywords

conjugated polymers; peptides; photopolymerization; self-assembly; supramolecular structures

Funding

  1. Johns Hopkins University
  2. Department of Energy's Office of Basic Energy Sciences (Biomolecular Materials program) [DE-SC0004857]
  3. Department of Chemistry at JHU

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Polydiacetylenes have received intense attention on account of their well-established chromic alterations that are detectable often by the naked eye, making them ideal for a variety of applications such as biosensory materials. These polymers have been fabricated in a variety of materials platforms including 3D crystals, 2D monolayers, and 0D spherical vesicles; however, 1D morphologies that might be useful for directional energy migration are less common. This article describes the development and current research efforts of protein-based 1D nanowire-like supramolecular assemblies with embedded polydiacetylenes.

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