Journal
MACROMOLECULAR RAPID COMMUNICATIONS
Volume 35, Issue 4, Pages 479-483Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/marc.201300695
Keywords
ADMET; Curtius rearrangement; fatty acids; polyurethane; solution
Categories
Funding
- University of Bordeaux-1
- ANR
- IPB
- CNRS
- Aquitaine Council
- ITERG
- ONIDOL
- ADEME agency
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A new route to ,-diene urethane monomer is proposed by converting 10-undecenoic acid into the corresponding acyl azide, followed by urethanization with 10-undecenol. ADMET polymerizations of this ,-diene urethane monomer as well as other bio-based ,-dienes bearing various organic functions (ester, carbonate, ether, amide) were carried out in bulk and solution conditions. A screening of the most commonly used metathesis catalysts allows to evaluate their tolerance toward the urethane function as well as toward Polarclean, a green and nontoxic high boiling point solvent. The influence of the nature of the central organic function in these ,-diene monomers on the thermomechanical properties is investigated.
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