Journal
MACROMOLECULAR RAPID COMMUNICATIONS
Volume 34, Issue 6, Pages 471-484Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/marc.201200788
Keywords
gas storage; hypercrosslinking; microporous polymers; networks; specific surface area
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Funding
- Program for Changjiang Scholars and Innovative Research Team in University [IRT1014]
- National Science Foundation of China [50973037, 51173058]
- Ministry of Education
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Hypercrosslinked polymers (HCPs) are currently receiving great interest due to their easy preparation, high chemical and thermal stability, and low cost. Combined with the lightweight properties and high surface areas HCPs can be considered as promising materials for gas storage and separation, catalysis, and heavy metal ions removal in wastewater treatment. This Feature Article summarizes strategies for the preparation of HCPs, comprising the post-crosslinking of Davankov-type resins, direct polycondensation of aromatic chloromethyl (or hydroxymethyl) monomers, and knitting aromatic compound polymers (KAPs). The HCPs applications, such as H2 storage, CO2 capture, and heterogeneous catalysis, are also discussed throughout in the article. Finally, the outlook of this research area is given.
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