Journal
MACROMOLECULAR RAPID COMMUNICATIONS
Volume 35, Issue 1, Pages 9-26Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/marc.201300712
Keywords
conjugated polymers; nanostructures; charge-transport properties
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Funding
- French National Agency (ANR) in the frame of its program in Nanosciences and Nanotechnologies (MYOSOTIS) [ANR-08-NANO-012-01]
- ANR [ANR-11-BS08-0009]
- Region Alsace
- IRTG project SOMAS
- Agence Nationale de la Recherche (ANR) [ANR-11-BS08-0009] Funding Source: Agence Nationale de la Recherche (ANR)
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The present review focuses on the recent progress made in thin film orientation of semi-conducting polymers with particular emphasis on methods using epitaxy and shear forces. The main results reported in this review deal with regioregular poly(3-alkylthiophene)s and poly(dialkylfluorenes). Correlations existing between processing conditions, macromolecular parameters and the resulting structures formed in thin films are underlined. It is shown that epitaxial orientation of semi-conducting polymers can generate a large palette of semi-crystalline and nanostructured morphologies by a subtle choice of the orienting substrates and growth conditions.
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