Journal
MACROMOLECULAR RAPID COMMUNICATIONS
Volume 33, Issue 6-7, Pages 540-544Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/marc.201100766
Keywords
conjugated polymers; metal complexes; metallopolymers; molecular assembly
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Novel p-conjugated compounds composed of fused salphen groups as a repeating unit, embedded with four or an indefinite number of zinc nuclei have been synthesized. The solid-state absorption spectra, IR spectra, and powder XRD patterns of these compounds are investigated and compared with those of analogous oligomers. The presumptive polymer contains at least five units of the salphen complex and its assembly is highly ordered in the solid state.
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