Journal
MACROMOLECULAR RAPID COMMUNICATIONS
Volume 33, Issue 2, Pages 107-113Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/marc.201100548
Keywords
atom transfer radical polymerization; colloids; macroporous polymers; polypyrroles; redox polymers
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Funding
- National Science Council of Taiwan
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The synthesis and electrochemical performance of three-dimensionally ordered macroporous (3DOM) nitroxide polymer brush electrodes for organic radical batteries are reported. The 3DOM electrodes are synthesized via polystyrene colloidal crystal templating with electropolymerization of polypyrrole, modification of surface initiator, and surface-initiated atom transfer radical polymerization. The discharge capacity of the 3DOM electrodes is proportional to the thickness of the inverse opal. The discharge capacity of the 3DOM electrode at a discharge rate of 5 C is 40 times higher than that of the planar electrode; its cycle-life performance exhibits 96.1% retention after 250 cycles.
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