Journal
MACROMOLECULAR RAPID COMMUNICATIONS
Volume 33, Issue 1, Pages 54-60Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/marc.201100611
Keywords
functional polymers primary structure; functional polymers; post-polymerization modification; nitroxide mediated polymerization (NMP)
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Funding
- CNRS
- University of Strasbourg
- International Center for Frontier Research in Chemistry (FRC, Strasbourg)
- European Research Council [258593]
- Grants-in-Aid for Scientific Research [10J07393] Funding Source: KAKEN
- European Research Council (ERC) [258593] Funding Source: European Research Council (ERC)
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The successful sequence-controlled installation of an activated ester using a newly designed monomer pentafluorophenyl 4-maleimidobenzoate is demonstrated. Pentafluorophenyl 4-maleimidobenzoate is kinetically installed at different stages of a nitroxide-mediated polymerization, namely, near the a-chain end and in the middle of a PS chain. In addition, successful installation of apolar and polar functional groups is achieved via post-polymerization functionalization, which demonstrated the versatility of the synthesis of a universal precursor for locally functionalized polymers.
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