Journal
MACROMOLECULAR RAPID COMMUNICATIONS
Volume 32, Issue 11, Pages 825-830Publisher
WILEY-BLACKWELL
DOI: 10.1002/marc.201100045
Keywords
conjugated polymers; diketopyrrolopyrrole; DPP; microporous materials; networks
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Funding
- BASF Schweiz AG, Basle, Switzerland
- Engineering and Physical Sciences Research Council [EP/E027431/1, EP/E036244/1] Funding Source: researchfish
- EPSRC [EP/E036244/1, EP/E027431/1] Funding Source: UKRI
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pi-Conjugated microporous networks have been prepared from the tetraarylated diketopyrrolo[3,4-c]pyrrole unit as a tetrafunctional building block. The reactions are carried out using microwave-assisted Yamamoto or Sonogashira cross-coupling. Red insoluble powders are obtained, showing intense fluorescence. The polymer networks exhibit a high gas storage capability, with BET surface areas up to about 500 m(2) . g(-1)
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