Journal
MACROMOLECULAR RAPID COMMUNICATIONS
Volume 31, Issue 9-10, Pages 934-938Publisher
WILEY-BLACKWELL
DOI: 10.1002/marc.201000104
Keywords
fibers; micelles; polyferrocenylsilane; self-assembly; seeded growth
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Funding
- Natural Sciences and Engineering Research Council of Canada
- European Union
- Royal Society
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Poly(ferrocenyldimethylsilane) (PFS) block copolymers form fiberlike micelles by a seeded growth process. This paper describes the effect of adding similar amounts of PFS block copolymers, PFS PDMS and PFS PI, to a common micelle seed. The lengths of the micelles obtained were strongly influenced by the degree of polymerization of the corona-forming blocks. The change in length was due to a change in the number of polymer molecules per unit length of the micelle.
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