Journal
MACROMOLECULAR RAPID COMMUNICATIONS
Volume 31, Issue 19, Pages 1696-1705Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/marc.201000114
Keywords
catalysis; beta-lactones; poly(hydroxyalkanoate)s; poly(3-hydroxybutyrate); ring-opening polymerization (ROP); stereospecific polymers; syndiotactic; yttrium
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Funding
- CNRS
- Agence Nationale de la Recherche [ANR-06-BLAN-0213]
- Region Bretagne (PRIR POLYBIO)
- Institut Unzversitaire de France
- Agence Nationale de la Recherche (ANR) [ANR-06-BLAN-0213] Funding Source: Agence Nationale de la Recherche (ANR)
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Poly(beta-hydroxyalkanoate)s (PHAs) are a class of aliphatic polyesters that can be efficiently synthesized by ring-opening polymerization (ROP) of beta-lactones. The case of chiral racemic beta-substituted beta-lactones is particularly appealing since these monomers open the way to original tacticities and materials different from those biotechnologically produced. In this overview, after briefly surveying general considerations associated to the ROP of beta-lactones and metal-based catalysts used in stereoselective ROP of racemic beta-butyrolactone, special emphasis is given to discrete rare earth catalysts that have allowed the preparation of highly syndiotactic poly(3-hydroxybutyrate)s. Recent developments such as preparation of stereo-controlled PHAs with pendant structural groups via (co)polymerization of functional beta-substituted beta-lactones, and highly alternating copolymers obtained by ROP of mixtures of enantiomerically pure but different monomers - are also discussed.
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