4.7 Article

Supramolecular Nanocycles Comprising β-Cyclodextrin-click-Ferrocene Units: Rings of Rings of Rings

Journal

MACROMOLECULAR RAPID COMMUNICATIONS
Volume 31, Issue 7, Pages 616-618

Publisher

WILEY-V C H VERLAG GMBH
DOI: 10.1002/marc.200900754

Keywords

cyclodextrin; ferrocene; supramolecular structures; TEM

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We applied 1,3-dipolar cycloaddition to bind ethynylferrocene onto 6I-azido-6I-deoxycyclo-maltoheptaose under microwave assisted conditions. The process was investigated by H-1 NMR, FT-IR spectroscopy, and MALDI-TOF mass spectrometry. The ability of the synthesized compound to self-organize to cyclic supramolecular structures was investigated by dynamic light scattering measurements and cryo-transmission electron microscopy.

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