Journal
MACROMOLECULAR RAPID COMMUNICATIONS
Volume 31, Issue 8, Pages 740-744Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/marc.200900764
Keywords
catalysis; cellulose; functionalization of polymers; polysaccharides; synthesis
Categories
Funding
- Swedish National Research Council, Angpanneforeningen
- Agricultural Sciences and Spatial Planning, Organoclick AB
- Stiftelsen Nils and Dorthi Troedssons Forskningsfond
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A simple and direct method for derivatization of solid polysaccharides is presented. The novel methodology is based on the combination of organic acid-catalyzed esterification or etherification and photochemical thiol-ene click derivatization of a heterogeneous polysaccharide. The solid cellulose was organoclick modified with aryl, alkyl and polyester groups, respectively. The modification allows for a highly modular and metal free surface modification of solid polysaccharides.
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