Journal
MACROMOLECULAR RAPID COMMUNICATIONS
Volume 30, Issue 8, Pages 622-626Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/marc.200800714
Keywords
block copolymers; morphology; nanofabrication; N-vinylcarbazole; photoconductor
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Funding
- Hong Kong Special Administrative Region, China [HKU7010/05P, HKU2/05C]
- Strategic Research Theme (HKU)
- Small Project Research Fund (HKU)
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The synthesis of poly(N-vinylcarbazole)-based block copolymers functionalized with rhenium diimine complexes or pendant terpyridine ligands is reported. The copolymers are synthesized by reversible addition-fragmentation chain transfer (RAFT) polymerization, and they exhibit interesting morphological properties as a result of the phase separation between different blocks. The rhenium complex polymer block may function as a photosensitizer, while the terpyridine-containing polymer block can be used as the template for nanofabrication by selective deposition of zinc complexes.
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