4.7 Article

A Triphenylamine-Based Conjugated Polymer with Donor-π-Acceptor Architecture as Organic Sensitizer for Dye-Sensitized Solar Cells

Journal

MACROMOLECULAR RAPID COMMUNICATIONS
Volume 30, Issue 18, Pages 1533-1537

Publisher

WILEY-V C H VERLAG GMBH
DOI: 10.1002/marc.200900243

Keywords

conjugated polymers; dyes/pigments; modeling; photochemistry; synthesis

Funding

  1. A-Star of Singapore [R-279-000-221-305]
  2. National Research Foundation of Singapore [R-279-000-276-272]

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A conjugated polymer containing an electron donating backbone (triphenylamine) and an electron accepting side chain (cyanoacetic acid) with conjugated thiophene units as the linkers has been synthesized. Dye-sensitized solar cells (DSSCs) are fabricated utilizing this material as the dye sensitizer, resulting a typical power conversion efficiency of 3.39% under AM 1.5 G illumination, which represents the highest efficiency for polymer dye-sensitized DSSCs reported so far. The results show the good promise of conjugated polymers as sensitizers for DSSC applications.

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