Journal
MACROMOLECULAR RAPID COMMUNICATIONS
Volume 29, Issue 16, Pages 1415-1420Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/marc.200800257
Keywords
conjugated polymers; films; light-emitting diodes (LED); luminescence; synthesis
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Funding
- NSFC of China [50573036]
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High molecular weight poly(9,10-bis(p-(2-ethylhexyloxy)phenyl)-2,6-anthracenevinylene) (2,6-PAV) was synthesized with 2,6-dimethylanthraquinone as a key intermediate. The as-synthesized polymer is readily soluble in common organic solvents and can be used for spin-coating. The as-synthesized polymer exhibits a broad absorption band ranging from 280 to 520 nm and a bluish green emission band with a peak at 500 nm. The polymer shows good thermal stability, and no distinct glass transition is observed. A simple device with the configuration ITO/PEDOT:PSS/2,6-PAV/Ba/Al showed a turn-on voltage of 4.8 V and a maximal brightness of 340 cd.m(-2).
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