4.7 Article

Polymers that contain ligated metals in their side chain: Building a foundation for functional materials in opto-electronic applications with an emphasis on lanthanide ions

Journal

MACROMOLECULAR RAPID COMMUNICATIONS
Volume 29, Issue 16, Pages 1355-1362

Publisher

WILEY-V C H VERLAG GMBH
DOI: 10.1002/marc.200800083

Keywords

functionalization of polymers; lanthanides; luminescence; metal-polymer complexes; opto-electronics

Funding

  1. ARO Young Investigator
  2. PECASE
  3. ONR Young Investigator
  4. NSF-CAREER
  5. 3M Non-tenured faculty
  6. Dupont Young Faculty Award

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Organic polymers that contain ligated metals offer a variety of unique properties which include luminescence, electro- and photochemistry, catalysis, charge, magnetism, and thermochromism. These organic-inorganic hybrid materials have the potential to offer novel active matrixes for advanced devices. Continued progress in synthetic chemistry and molecular characterization will enable such advanced materials. Here the focus is restricted to side-chain metal complexes with emissive properties that highlight the use of lanthanide ions as opposed to the often-studied transition metal complexes.

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