4.5 Article

Co-Injection Molded New Green Composites from Biodegradable Polyesters and Miscanthus Fibers

Journal

MACROMOLECULAR MATERIALS AND ENGINEERING
Volume 299, Issue 4, Pages 436-446

Publisher

WILEY-V C H VERLAG GMBH
DOI: 10.1002/mame.201300189

Keywords

biodegradable; biopolymers; co-injection molding; green composites; impact resistance

Funding

  1. Ontario Ministry of Agriculture and Food (OMAF)
  2. Ministry of Rural Affairs (MRA)
  3. New Directions Research Program [SR9211]
  4. OMAF
  5. MRA Highly Qualified Personal program (HQP)

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A novel concept of developing green composites with improved performance using co-injection molding technique has been established. Poly (butylene succinate) (PBS), poly (butylene adipate-co-terephtalate) (PBAT), and their blends were investigated as skin material. Composite core material was made from poly (3-hydroxybutyrate-co-hydroxyvalerate) (PHBV) and miscanthus. Co-injected samples with good surface finish were achieved at a skin/core volume ratio of 40/60 and mold temperature of 45 degrees C. Notched impact strength of 140J/m, four times higher than that of neat core material and unnotched impact strength of almost 400J/m with modulus of more than 1GPa was achieved for the co-injection molded green composites. Good adhesion at the skin/core interface was observed under scanning electron microscopy.

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